Effect of rapid thermal processing conditions on the properties of Cu2ZnSnS4 thin films and solar cell performance

In the present work, we have studied the effect of several sulphurization conditions on the properties of Cu2ZnSnS4 thin films obtained through rapid thermal processing (RTP) of multi-period precursors with 8 periods of Zn/SnS2/CuS. In this study we varied the heating rate, the maximum sulphurization temperature, the time at maximum temperature and the amount of evaporated sulphur. The samples were characterized through scanning electron microscopy, energy dispersive spectroscopy, Raman scattering spectroscopy, X-ray diffraction, photoluminescence and I–V measurements. We have observed that at heating rates above 0.5 1C/s the samples delaminated severely. As a result further tests were carried out at 0.2 1C/s heating rate. The morphological studies revealed that the samples sulphurized at higher temperatures, shorter times and higher amount of evaporated sulphur exhibited larger grain sizes. The structural analysis based on Raman scattering and XRD did not lead to a clear distinction between the samples. Photoluminescence spectroscopy studies showed an asymmetric broad band characteristic of CZTS, which occurs in the range of 1.0–1.4 eV and a second band, on the high energy side of the previous one, peaking at around 1.41 eV. The intensity of this latter band varies from sample to sample revealing substantial differences in their optical properties. This band appears to originate either from the surface of the absorber or from the CdS layer and has a clear correlation with cell efficiency. The higher the intensity of this band the lower the cell efficiency, presumably due to the increase in recombination resulting from CZTS surface decomposition and eventually from the CdS with modified optoelectronic properties. The cell results hint toward a detrimental effect of long sulphuriza-tion times and a positive effect of higher sulphur vapour pressure and higher sulphurization temperature. Solar cell efficiencies improved with increased grain size in the absorber layer. The highest cell efficiency obtained in this study was 3.1%.info:eu-repo/semantics/publishedVersio

Impacts of climate changes on risk zoning for cowpea in the Amazonian tropical conditions

The climate risk zoning was carried out for cowpea cultivated in northeastern Amazonia, Pará state, Brazil. Système d’Analyse Régionale des Risques Agroclimatologiques (SARRA) crop model was used and calibrated from data obtained in field experiments conducted between 2013 and 2016 in Castanhal, state of Pará. Low climate risk areas were defined as those with water requirement satisfaction index (WRSI) greater than or equal to 0.5 during flowering and early grain development and less than 20 mm of total rainfall during grain maturation and harvest for at least 80% of the simulated sowings of the crop. Simulations of the current and future climate conditions were carried out with the regional climate modelling system version 4 (RegCM4) nested with the HadGEM2 global circulation model with RCP 4.5 IPCC-AR4 scenario. The results show that climate changes are likely to reduce the duration of the optimal period for sowing cowpea in the mentioned regioninfo:eu-repo/semantics/publishedVersio

Comparative Study of the Response of Kinematical Variables from the Hip and the Center of Mass in Butterfliers

The aim of this study was to compare the intracyclic variation of kinematical variables from the hip and the center of mass (CM) with the purpose to assess if the analysis of kinematical variables of the hip might replace the study of the kinematical variables of the CM. Seven Portuguese male swimmers of national and intemational levei were studied. Each swimmer performed 3 sets of3x25 meters, at a constant velocity and as close as possible to the maximum, using exclusively frontal inspiration cycles, lateral inspiration cycles and non-inspiratory cycles in each set. Two pairs of cameras were used to create "dual media" images. Another cam era was set behind an underwater window in the endwall. One last camera was placed above the water surface. The study comprised the analysis of complete stroke cycles in buttert1y using the "Ariel Performance Analysis System" from Ariel Dynamics Inc. Some of the correlations between the maximal vertical amplitude of displacement of the hip and the CM didn't present significant values. AlI the correlations between the horizontal velocity and horizontal acceleration of the hip and the CM were significant in all breathing models. However, only one swimmer presented in both cases r>=O.95. So, apparently, the hip does not represent properly the intracyclic variations ofthe kinematical variables ofthe CM.info:eu-repo/semantics/publishedVersio

Influence of landscape features and management practices in olive groves for optimized pest control

Trabalho apresentado em XI European Congress Of Entomology, 2-6 July 2018, Nápoles, Itália.N/

Microelectromechanical resonators based on an all polymer/carbon nanotube composite structural material

Carboxylated multi-wall carbon-nanotubes (CNTs) monolayers are integrated on microfabricated all-polymer micro-electromechanical systems (pMEMS) resonator bridges on glass substrates. The structural layer of the MEMS bridges is a multilayer blended conductive polymer based on poly(3,4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT:PSS) to which functionalized CNT monolayers are electrostatically attached. The resonance frequency (fres) of electrostatically actuated pMEMS bridges was measured as a function of their length (32–67 lm) for different multilayer compositions. A significant increase in fres and quality factor (Q) with the addition of CNT monolayers to the PEDOT:PSS structural material is observed, demonstrating that CNT monolayers can be used to modulate pMEMS resonator properties.Peer ReviewedPostprint (published version

Diversity of bacterial biosynthetic genes in maritime antarctica

Bacterial natural products (NPs) are still a major source of new drug leads. Polyketides (PKs) and non-ribosomal peptides (NRP) are two pharmaceutically important families of NPs and recent studies have revealed Antarctica to harbor endemic polyketide synthase (PKS) and non-ribosomal peptide synthetase (NRPS) genes, likely to be involved in the production of novel metabolites. Despite this, the diversity of secondary metabolites genes in Antarctica is still poorly explored. In this study, a computational bioprospection approach was employed to study the diversity and identity of PKS and NRPS genes to one of the most biodiverse areas in maritime Antarctica—Maxwell Bay. Amplicon sequencing of soil samples targeting ketosynthase (KS) and adenylation (AD) domains of PKS and NRPS genes, respectively, revealed abundant and unexplored chemical diversity in this peninsula. About 20% of AD domain sequences were only distantly related to characterized biosynthetic genes. Several PKS and NRPS genes were found to be closely associated to recently described metabolites including those from uncultured and candidate phyla. The combination of new approaches in computational biology and new culture-dependent and -independent strategies is thus critical for the recovery of the potential novel chemistry encoded in Antarctica microorganisms.Fundação para a Ciência e a Tecnologia (FCT) funded this study through the grant PTDC/CTA- AMB/30997/2017 to CM, the IF research contract IF/01358/2014 to PNL, a PhD scholarship to AR (SFRH/BD/140567/2018) and within the scope of UIDB/04423/2020 and UIDP/04423/2020. The authors acknowledge the Portuguese Polar Program (PROPOLAR) and the Chilean Antarctic Institute (INACH) for providing logistics and traveling financial support during CONTANTARC-3 campaign in Maxwell Bay/King George Island

Burnout num hospital pediátrico

[resumo][abstract

Glutamate-N-methyl-D-aspartate receptor modulation and minocycline for the treatment of patients with schizophrenia: an update

Growing consistent evidence indicates that hypofunction of N-methyl-D-aspartate (NMDA) transmission plays a pivotal role in the neuropathophysiology of schizophrenia. Hence, drugs which modulate NMDA neurotransmission are promising approaches to the treatment of schizophrenia. The aim of this article is to review clinical trials with novel compounds acting on the NMDA receptor (NMDA-R). This review also includes a discussion and translation of neuroscience into schizophrenia therapeutics. Although the precise mechanism of action of minocycline in the brain remains unclear, there is evidence that it blocks the neurotoxicity of NMDA antagonists and may exert a differential effect on NMDA signaling pathways. We, therefore, hypothesize that the effects of minocycline on the brain may be partially modulated by the NMDA-R or related mechanisms. Thus, we have included a review of minocycline neuroscience. The search was performed in the PubMed, Web of Science, SciELO, and Lilacs databases. The results of glycine and D-cycloserine trials were conflicting regarding effectiveness on the negative and cognitive symptoms of schizophrenia. D-serine and D-alanine showed a potential effect on negative symptoms and on cognitive deficits. Sarcosine data indicated a considerable improvement as adjunctive therapy. Finally, minocycline add-on treatment appears to be effective on a broad range of psychopathology in patients with schizophrenia. The differential modulation of NMDA-R neurosystems, in particular synaptic versus extrasynaptic NMDA-R activation and specific subtypes of NMDA-R, may be the key mediators of neurogenesis and neuroprotection. Thus, psychotropics modulating NMDA-R neurotransmission may represent future monotherapy or add-on treatment strategies in the treatment of schizophrenia

Identifying and prioritising services in European terrestrial and freshwater ecosystems

Ecosystems are multifunctional and provide humanity with a broad array of vital services. Effective management of services requires an improved evidence base, identifying the role of ecosystems in delivering multiple services, which can assist policy-makers in maintaining them. Here, information from the literature and scientific experts was used to systematically document the importance of services and identify trends in their use and status over time for the main terrestrial and freshwater ecosystems in Europe. The results from this review show that intensively managed ecosystems contribute mostly to vital provisioning services (e.g. agro-ecosystems provide food via crops and livestock, and forests provide wood), while semi-natural ecosystems (e.g. grasslands and mountains) are key contributors of genetic resources and cultural services (e.g. aesthetic values and sense of place). The most recent European trends in human use of services show increases in demand for crops from agro-ecosystems, timber from forests, water flow regulation from rivers, wetlands and mountains, and recreation and ecotourism in most ecosystems, but decreases in livestock production, freshwater capture fisheries, wild foods and virtually all services associated with ecosystems which have considerably decreased in area (e.g. semi-natural grasslands). The condition of the majority of services show either a degraded or mixed status across Europe with the exception of recent enhancements in timber production in forests and mountains, freshwater provision, water/erosion/natural hazard regulation and recreation/ecotourism in mountains, and climate regulation in forests. Key gaps in knowledge were evident for certain services across all ecosystems, including the provision of biochemicals and natural medicines, genetic resources and the regulating services of seed dispersal, pest/disease regulation and invasion resistance

Conhecendo o IAF do cafeeiro arábica através do índice de vegetação por diferença normalizada

O objetivo deste trabalho foi relacionar a série temporal do Índice de Área Foliar (IAF) estimado pelo método proposto por Barbosa et al. (2012) ao índice de vegetação por diferença normalizada (NDVI) adequando um modelo de determinação do IAF através de dados de NDVI coletados em um cafezal na região de Lavras, sul de Minas Gerais. Para isso foi realizado o estudo em cafezal no campus da Universidade Federal de Lavras (UFLA) no período de fevereiro de 2014 a fevereiro de 2015 onde trinta plantas de Coffea arabica L, cv Catuaí IAC 144 foram avaliadas mensalmente com medições de altura do ramo ortotrópico e comprimento de plagiotrópicos em 5 posições na copa para estimativa do IAF, enquanto as avaliações de NDVI foram realizadas semanalmente em três posições distintas da planta. Dados mensais de precipitação (mm- Prec) e temperatura média do ar (°C- Tm) também foram coletados. Os valores de cada variável foram submetidos à análise de correlação (r). A série temporal demonstra que o IAF varia em função da temperatura e precipitação. O modelo de regressão exponencial foi o mais adequado para determinar os valores de IAF em função do NDVI. As correlações do IAF com o NDVI variam em função da posição da medida de NDVI da planta. A série temporal do IAF é uma variável útil nas práticas de manejo, enquanto NDVI pode ser utilizado para determinar o IAF em plantas de café